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(2alpha,6alpha,11R*)-1,2,3,4,5,6-hexahydro-6,11-dimethyl-2,6-methano-3-benzazocin-8-ol

CAS No.: 25144-78-9

product details:

Purity: 99%

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Quality Manufacturer Supply High Purity 99% (2alpha,6alpha,11R*)-1,2,3,4,5,6-hexahydro-6,11-dimethyl-2,6-methano-3-benzazocin-8-ol 25144-78-9 with Reasonable Price

  • Molecular Formula: C14H19NO
  • Molecular Weight: 217.311
  • Boiling Point: 355.8°Cat760mmHg 
  • PKA: 9.79±0.60(Predicted) 
  • Flash Point: 128°C 
  • PSA: 32.26000 
  • Density: g/cm3 
  • LogP: 2.53280 

25144-78-9 Relevant articles

A new synthesis of 6,7 benzomorphan

Shiotani,Kometani,Futsukaichi,Mitsuhashi

, p. 1106 - 1108 (2007/10/11)

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25144-78-9 Process route

8-Hydroxy-2,6-methano-6α,11α-dimethyl-1,2,3,4,5,6-hexahydro-3-benzazocin
16603-67-1,16670-83-0,16670-84-1,16670-86-3,16671-00-4,16808-63-2,25144-77-8,25144-78-9,52079-30-8

8-Hydroxy-2,6-methano-6α,11α-dimethyl-1,2,3,4,5,6-hexahydro-3-benzazocin

Conditions
Conditions Yield
3-Benzyl-8-hydroxy-2,6-methano-6α,11α-dimethyl-1,2,3,4,5,6-hexahydro-3-benzazocin-hydrochlorid, H2, Pd/C;
(yield)90.1percent;
3-Benzyl-1,2,3,4,5,6-hexahydro-cis-6,11-dimethyl-2,6-methano-3-benzazocin-8-ol, H2, Pd/C;
entspr. (6)-N-oxid, red. Spaltung;
6,11<i>syn</i>-dimethyl-1,2,3,4,5,6-hexahydro-2,6-methano-benz[<i>d</i>]azocin-8-ol
16603-67-1,16670-83-0,16670-84-1,16670-86-3,16671-00-4,16808-63-2,25144-77-8,25144-78-9,52079-30-8

6,11syn -dimethyl-1,2,3,4,5,6-hexahydro-2,6-methano-benz[d ]azocin-8-ol

Conditions
Conditions Yield
With acetic anhydride; Erwaermen des Reaktionsprodukts mit Bromcyan in Chloroform und Erhitzen des nach dem Eindampfen erhaltenen Rueckstandes mit wss. Salzsaeure.;

25144-78-9 Downstream products

  • 26918-40-1
    26918-40-1

    3-benzyl-6,11-dimethyl-1,2,3,4,5,6-hexahydro-2,6-methano-benzo[d ]azocin-8-ol; hydrobromide

  • 3734-52-9
    3734-52-9

    (-)-Metazocine

  • 359-83-1
    359-83-1

    (-)-Pentazocine

  • 3572-80-3
    3572-80-3

    (-)-Cyclazocine

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