3,5-Dimethoxytoluene

CAS No.: 4179-19-5

product details:

Purity: 99%

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  • Molecular Formula: C9H12O2
  • Molecular Weight: 152.193
  • Appearance/Colour: Clear colorless to yellow liquid 
  • Vapor Pressure: 0.0486mmHg at 25°C 
  • Melting Point: 61-62 °C 
  • Refractive Index: n20/D 1.522(lit.)  
  • Boiling Point: 244 °C at 760 mmHg 
  • Flash Point: 87.5 °C 
  • PSA: 18.46000 
  • Density: 0.99 g/cm3 
  • LogP: 2.01220 

3,5-Dimethoxytoluene(Cas 4179-19-5) Usage

Synthesis Reference(s)

Organic Syntheses, Coll. Vol. 6, p. 859, 1988The Journal of Organic Chemistry, 70, p. 3275, 2005 DOI: 10.1021/jo050075r

General Description

3,5-Dimethoxytoluene (DMT) is a methoxylated phenolic derivative. It is reported to be one of the main constituent of the floral volatiles in different rose varieties. It has been biosynthesized from orcinol by two successive methylation catalyzed by O-methyltransferases (OMTs). The features of its aerobic oxidation with metal/bromide catalysts have been investigated.

InChI:InChI=1/C9H12O2/c1-7-4-8(10-2)6-9(5-7)11-3/h4-6H,1-3H3

4179-19-5 Relevant articles

Organochlorine compounds from a terrestrial higher plant: Structures and origin of chlorinated orcinol derivatives from diseased bulbs of Lilium maximowiczii

Monde, Kenji,Satoh, Hikari,Nakamura, Masao,Tamura, Mamoru,Takasugi, Mitsuo

, p. 913 - 921 (1998)

Seven chlorine-containing orcinol deriva...

An Asymmetric Synthesis of Hamigeran B via a Pd Asymmetric Allylic Alkylation for Enantiodiscrimination

Trost, Barry M.,Pissot-Soldermann, Carole,Chen, Irwin,Schroeder, Gretchen M.

, p. 4480 - 4481 (2004)

A protocol for the asymmetric allylic al...

Radical induced disproportionation of alcohols assisted by iodide under acidic conditions

Huang, Yang,Jiang, Haiwei,Li, Teng,Peng, Yang,Rong, Nianxin,Shi, Hexian,Yang, Weiran

supporting information, p. 8108 - 8115 (2021/10/29)

The disproportionation of alcohols witho...

Metal-Free Heterogeneous Semiconductor for Visible-Light Photocatalytic Decarboxylation of Carboxylic Acids

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A suitable protocol for the photocatalyt...

Molybdenum-Catalyzed Deoxygenation Coupling of Lignin-Derived Alcohols for Functionalized Bibenzyl Chemicals

Jiang, Huifang,Lu, Rui,Luo, Xiaolin,Si, Xiaoqin,Xu, Jie,Lu, Fang

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With the growing demand for sustainabili...

Method for hydrogenolysis of halides

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Paragraph 0232; 0296-0298, (2021/01/11)

The invention discloses a method for hyd...

4179-19-5 Process route

orcinol
504-15-4

orcinol

methyl iodide
74-88-4

methyl iodide

O-methylorcinol
3209-13-0

O-methylorcinol

1,3-dimethoxy-5-methylbenzene
4179-19-5

1,3-dimethoxy-5-methylbenzene

Conditions
Conditions Yield
With methanol; potassium hydroxide;
orcinol
504-15-4

orcinol

methanol
67-56-1

methanol

methyl iodide
74-88-4

methyl iodide

O-methylorcinol
3209-13-0

O-methylorcinol

1,3-dimethoxy-5-methylbenzene
4179-19-5

1,3-dimethoxy-5-methylbenzene

Conditions
Conditions Yield

4179-19-5 Upstream products

  • 504-15-4
    504-15-4

    orcinol

  • 77-78-1
    77-78-1

    dimethyl sulfate

  • 3209-13-0
    3209-13-0

    O-methylorcinol

  • 74-88-4
    74-88-4

    methyl iodide

4179-19-5 Downstream products

  • 854678-27-6
    854678-27-6

    4-(2,4-dimethoxy-6-methyl-phenyl)-4-oxo-butyric acid

  • 20872-08-6
    20872-08-6

    2,6-dimethoxy-4-methylbenzoic acid

  • 7149-90-8
    7149-90-8

    2,4-dimethoxy-6-methyl-benzaldehyde

  • 855890-69-6
    855890-69-6

    1-(2-hydroxy-4-methoxy-6-methyl-phenyl)-heptadecan-1-one

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